Structure and Heat Resistance of Intermetallic Rhenium-Containing Alloy after Heat Treatment
Authors: Arginbaeva E.G., Bazyleva O.A., Karachevtsev F.N., Nazarkin R.М | Published: 20.12.2019 |
Published in issue: #6(129)/2019 | |
Category: Aviation and Rocket-Space Engineering | Chapter: Innovation Technologies of Aerospace Engineering | |
Keywords: intermetallics, nickel, heat treatment, structure, phase, misfit |
The developed intermetallic Ni3Al compound-based alloys, known under the VKNA (ВКНА) and VIN (ВИН) brands, attract attention due to high operating temperatures --- up to 1200 °C, and relatively low density --- ~ 8 g / cm3. The first-generation intermetallic alloys such as VKNA-1V (ВКНА-1В) and VKNA-4U (ВКНА-4У) are known not to require multi-stage heat treatment. An increase in the strength characteristics caused by high requirements for the hot gas path materials also occurs due to an increase of high-melt alloying elements. Therefore, investigations in the field of temperature effects on the structure and properties of new generation intermetallic alloys become very relevant. In our research we studied the influence of heat treatment on the structural phase state of the VIN4 (ВИН4) intermetallic alloy containing rhenium. Findings show that annealing at close to solvus temperatures allows increasing the time to failure during 1100 °C stress-rupture strength tests. At the same time, during the heat treatment of the alloy with a high cooling rate, elements are redistributed with uneven allocation of phases of different morphology enriched in molybdenum and chromium, which negatively affects the results of stress- rupture strength. The research is an intermediate step in establishing patterns of influence of heat treatment parameters on intermetallic alloys depending on the degree of alloying
The work was supported by the RFBR grant no. 16-38-00260 "Study of the laws of formation of the structural-phase state of heat-resistant foundry intermetallic alloys based on nickel after various heat treatment modes"
References
[1] Kablov E.N., ed. Istoriya aviatsionnogo materialovedeniya. VIAM --- 75 let poiska, tvorchestva, otkrytiy [History of aviation material engineering. VIAM --- 75 years of research, art, discoveries]. Moscow, Nauka Publ., 2007.
[2] Kablov E.N., Petrushin N.V., Vasilenok L.B., et al. Rhenium in heatproof nickel-based alloys for gas turbine blades. Materialovedenie, 2000, no. 2, pp. 23--29 (in Russ.).
[3] Kablov E.N., Petrushin N.V., Vasilenok L.B., et al. Rhenium in heatproof nickel-based alloys for gas turbine blades (continuation). Materialovedenie, 2000, no. 3, pp. 38--43 (in Russ.).
[4] Kablov E.N., Buntushkin V.P., Morozova G.I., et al. Main doping principles for Ni3Al intermetallic at production of heatproof alloys. Materialovedenie, 1998, no. 7, pp. 13--15 (in Russ.).
[5] Bazyleva O.A., Arginbaeva E.G., Turenko E.Yu. High-temperature casting intermetallic alloys. Aviatsionnye materialy i tekhnologii [Aviation Materials and Technologies], 2012, no. S, pp. 57--60 (in Russ.).
[6] Bazyleva O.A., Turenko E.Yu., Arginbaeva E.G. The high-temperature intermetallic alloys for parts of gas-turbine engines. Aviatsionnye materialy i tekhnologii [Aviation Materials and Technologies], 2013, no. 3, pp. 26--31 (in Russ.).
[7] Jozwik P., Polkowski W., Bojar Z. Applications of Ni3Al based intermetallic alloys --- current stage and potential perceptivities materials. Materials, 2015, vol. 8, no. 5, pp. 2537--2568. DOI: 10.3390/ma8052537
[8] Bazyleva O.A., Arginbaeva E.G., Fesenko T.V., et al. Influence study of liquation on structure and durability of intermetallic alloys based on nickel. Materialovedenie, 2014, no. 6, pp. 7--12 (in Russ.).
[9] Arginbaeva E.G. Vliyanie legirovaniya, tekhnologiy lit’ya i termicheskoy obrabotki na strukturu i svoystva intermetallidnykh splavov na osnove nikelya. Avtoref. dis. kand. tekh. nauk [Effect of doping, casting technology and thermal treatment on structure and properties of Ni-based intermetallic alloys. Abs. Сand. Sc. (Eng.) Diss.]. Moscow, VIAM Publ., 2014 (in Russ.).
[10] Kablov E.N. Innovative developments of FSUE "VIAM" SSC of RF on realization of "Strategic directions of the development of materials and technologies of their processing for the period until 2030". Aviatsionnye materialy i tekhnologii [Aviation Materials and Technologies], 2015, no. 1, pp. 3--33 (in Russ.).
[11] Kablov E.N., Ospennikova O.G., Lomberg B.S. Strategic growth option of construction materials and their treatment technologies for present and future aviation engines. Avtomaticheskaya svarka, 2013, no. 10-11, pp. 23--32 (in Russ.).
[12] Samoylov A.I., Nazarkin R.M., Moiseeva N.S. The lattice misfit determination in fragmented single crystals of nickel-based superalloy. Trudy VIAM [Proceedings of VIAM], 2013, no. 5 (in Russ.). Available at: http://www.viam-works.ru/plugins/content/journal/uploads/articles/pdf/33.pdf
[13] Semenov V.N., Bondarev B.I., Fatkullin O.Kh., et al. Sposob termicheskoy obrabotki zharoprochnykh splavov na osnove nikelya [Heat treatment method for heatproof Ni-based alloys]. Patent 2164262 RF. Appl. 20.11.1998, publ. 20.03.2011 (in Russ.).
[14] Neumeier S., Pyczak F., Goken M. The influence of ruthenium and rhenium on the local properties of the γ- and γ’-phase in Ni-based single crystal superalloys and their consequences for alloy behaviour. Superalloys-2008. 11th Int. Symp. Superalloys, 2008, pp. 109--119.
[15] Saito S., Kurokawa K., Hayashi Sh., et al. Tie-line compositions of the σ and (γ, γ’, β) phases in the Ni--Al--Re--Cr system at 1423 K. ECS Trans., 2009, vol. 16, no. 44, pp. 177--184. DOI: 10.1149/1.3224754
[16] Zhu J., Cao W., Yang Y., et al. Chang application of the cluster/site approximation to FCC phases in the Ni--Al--Cr--Re system. Acta Mater., 2007, vol. 55, no. 13, pp. 4545--4551. DOI: 10.1016/j.actamat.2007.04.019
[17] Li P., Li Sh.S., Han Ya.F. Influence of solution heat treatment on microstructure and stress rupture properties of a Ni3Al base single crystal superalloy IC6SX. Intermetallics, 2011, vol. 19, no. 2, pp. 182--186. DOI: 10.1016/j.intermet.2010.08.019
[18] Li H., Li F., Li Sh., et al. Influence of ageing treatments on stress rupture properties of Ni3Al base single crystal alloy IC21 at 850 °C. Mat. Sc. Forum, 2013, vol. 747-748, pp. 659--664. DOI: 10.4028/www.scientific.net/MSF.747-748.659
[19] Ai Ch., Li Sh., Zhang H., et al. Effect of withdrawal rate on microstructure and lattice misfit of a Ni3Al based single crystal superalloy. J. Alloys Compd., 2014, vol. 592, pp. 164--169. DOI: 10.1016/j.jallcom.2013.12.262